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dc.creatorPringle, Wallace C.en_US
dc.creatorChang, Daviden_US
dc.date.accessioned2006-06-15T16:52:04Z
dc.date.available2006-06-15T16:52:04Z
dc.date.issued1969en_US
dc.identifier1969-M-9en_US
dc.identifier.urihttp://hdl.handle.net/1811/15768
dc.descriptionThis work was supported by the Connecticut Research Commission. $^{1}$ M. Mizushima and P. Venkateswarlu, J. Chem. Phys. 21, 705 (1953); M. Mizushima, ibid. 21, 1222 (1953).en_US
dc.descriptionAuthor Institution: Department of Chemistry, Science Center, Wesleyan University, Middletownen_US
dc.description.abstractThe pressure-induced infrared spectrum due to the quadrupole in allene has been observed from 300 to $190 cm^{-1}$. Pressures up to 5 atm in allene were used at a path length of 10m. The absorbance depended on the square of the pressure as expected for collision-induced transitions. The relation of this phenomenon to the predicted absorbance due to rotational transitions in the allene molecule within odd excited degenerate vibrational $states,^{1}$ which should have a linear dependence on the pressure, will be discussed. Extension of the measurements into the far-infrared region will also be presented.en_US
dc.format.extent117400 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titlePRESSURE INDUCED INFRARED SPECTRUM OF ALLENE.en_US
dc.typearticleen_US


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