RAMAN SPECTRUM OF $NaClO_{3}$ AT VERY HIGH PRESSURES.
dc.creator | Ellenson, William D. | en_US |
dc.creator | Nicol, Malcolm F. | en_US |
dc.date.accessioned | 2006-06-15T16:49:48Z | |
dc.date.available | 2006-06-15T16:49:48Z | |
dc.date.issued | 1969 | en_US |
dc.identifier | 1969-D-13 | en_US |
dc.identifier.uri | http://hdl.handle.net/1811/15680 | |
dc.description | Author Institution: Department of Chemistry, University of California | en_US |
dc.description.abstract | Raman spectra of single crystals of $NaClO_{3}$ have been studied at atmospheric pressure and elevated pressures as high as 35 kbar. The frequencies of all of the vibrational modes increase with increasing pressure. Between 1 atm. and 30 kbar, $\nu_{1}$ (A) increases by $12 cm^{-1}$; both the A and F components of $\nu_{2}$ increase by $8 cm^{-1}$; and the E and F components of $\nu_{4}$ increase by $9 cm^{-1}$. For the same charge of pressure, the $957-cm^{-1}$ (E) component of $\nu_{2}$ shifts $+ 16 cm^{-1}$; the $967-cm^{-1}$ (F) component shifts $+ 18 cm^{-1}$, the $989-cm^{-1}$ (F, transverse) component shifts $+ 17 cm^{-1}$, and the $1029-cm^{-1}$ (F, longitudinal) component shifts $+20 cm^{-1}$. Effects of pressure on the frequencies of the external lattice modes also will be discussed. | en_US |
dc.format.extent | 108089 bytes | |
dc.format.mimetype | image/jpeg | |
dc.language.iso | English | en_US |
dc.publisher | Ohio State University | en_US |
dc.title | RAMAN SPECTRUM OF $NaClO_{3}$ AT VERY HIGH PRESSURES. | en_US |
dc.type | article | en_US |
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