dc.creator Ellenson, William D. en_US dc.creator Nicol, Malcolm F. en_US dc.date.accessioned 2006-06-15T16:49:48Z dc.date.available 2006-06-15T16:49:48Z dc.date.issued 1969 en_US dc.identifier 1969-D-13 en_US dc.identifier.uri http://hdl.handle.net/1811/15680 dc.description Author Institution: Department of Chemistry, University of California en_US dc.description.abstract Raman spectra of single crystals of $NaClO_{3}$ have been studied at atmospheric pressure and elevated pressures as high as 35 kbar. The frequencies of all of the vibrational modes increase with increasing pressure. Between 1 atm. and 30 kbar, $\nu_{1}$ (A) increases by $12 cm^{-1}$; both the A and F components of $\nu_{2}$ increase by $8 cm^{-1}$; and the E and F components of $\nu_{4}$ increase by $9 cm^{-1}$. For the same charge of pressure, the $957-cm^{-1}$ (E) component of $\nu_{2}$ shifts $+ 16 cm^{-1}$; the $967-cm^{-1}$ (F) component shifts $+ 18 cm^{-1}$, the $989-cm^{-1}$ (F, transverse) component shifts $+ 17 cm^{-1}$, and the $1029-cm^{-1}$ (F, longitudinal) component shifts $+20 cm^{-1}$. Effects of pressure on the frequencies of the external lattice modes also will be discussed. en_US dc.format.extent 108089 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title RAMAN SPECTRUM OF $NaClO_{3}$ AT VERY HIGH PRESSURES. en_US dc.type article en_US
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