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dc.creatorEllenson, William D.en_US
dc.creatorNicol, Malcolm F.en_US
dc.date.accessioned2006-06-15T16:49:48Z
dc.date.available2006-06-15T16:49:48Z
dc.date.issued1969en_US
dc.identifier1969-D-13en_US
dc.identifier.urihttp://hdl.handle.net/1811/15680
dc.descriptionAuthor Institution: Department of Chemistry, University of Californiaen_US
dc.description.abstractRaman spectra of single crystals of $NaClO_{3}$ have been studied at atmospheric pressure and elevated pressures as high as 35 kbar. The frequencies of all of the vibrational modes increase with increasing pressure. Between 1 atm. and 30 kbar, $\nu_{1}$ (A) increases by $12 cm^{-1}$; both the A and F components of $\nu_{2}$ increase by $8 cm^{-1}$; and the E and F components of $\nu_{4}$ increase by $9 cm^{-1}$. For the same charge of pressure, the $957-cm^{-1}$ (E) component of $\nu_{2}$ shifts $+ 16 cm^{-1}$; the $967-cm^{-1}$ (F) component shifts $+ 18 cm^{-1}$, the $989-cm^{-1}$ (F, transverse) component shifts $+ 17 cm^{-1}$, and the $1029-cm^{-1}$ (F, longitudinal) component shifts $+20 cm^{-1}$. Effects of pressure on the frequencies of the external lattice modes also will be discussed.en_US
dc.format.extent108089 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleRAMAN SPECTRUM OF $NaClO_{3}$ AT VERY HIGH PRESSURES.en_US
dc.typearticleen_US


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