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dc.creatorTipping, R. H.en_US
dc.creatorHerman, R. M.en_US
dc.date.accessioned2006-06-15T16:48:55Z
dc.date.available2006-06-15T16:48:55Z
dc.date.issued1968en_US
dc.identifier1968-Z-4en_US
dc.identifier.urihttp://hdl.handle.net/1811/15645
dc.descriptionAuthor Institution: Department of Physics, Osmond Laboratory, The Pennsylvania State Universityen_US
dc.description.abstractThe noble gas pressure-broadened rotation line widths and shifts have been calculated within the impact approximation. The intermolecular potential employed included the long- and short-range behavior of the isotropic part together with the anisotropic terms of $P_{1} (\cos \theta)$ symmetry arising from the separation of the dynamical and electrical centers in HCl. $P_{2} (\cos \theta)$ terms were found to have negligible effect. Bent trajectories, which realistically represent the HCl-noble gas collision, have been assumed, and velocity averaging was explicitly performed. The results are quite sensitive to the latter. The theoretical results compare well with experiment, in that the calculated widths and shifts of most of the lines, as broadened by each of the rare gases, fall within 20% of the corresponding experimental values.en_US
dc.format.extent129307 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titlePRESSURE BROADENING AND SHIFTING OF HCl LINES BY NOBLE GASESen_US
dc.typearticleen_US


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