dc.creator McCaffery, A. J. en_US dc.creator Schatz, P. N. en_US dc.creator Lester, T. E. en_US dc.date.accessioned 2006-06-15T16:45:27Z dc.date.available 2006-06-15T16:45:27Z dc.date.issued 1968 en_US dc.identifier 1968-K-8 en_US dc.identifier.uri http://hdl.handle.net/1811/15507 dc.description This work was supported by a grant from the National Science Foundation. en_US dc.description Author Institution: Department of Chemistry, University of Virginia en_US dc.description.abstract The magnetic circular dichroism (MCD) of $IrCl_{6}^{2-}$ doped into $(CH_{***}NH_{3})_{2} SnCl_{6}$ has been studied as a function of temperature from liquid helium to room temperature over the region 7000-3000 {\AA}. The results confirm the new assignment (based on solution MCD data) of the first two allowed charge-transfer bands so that the $^{2}T_{1u}$ state lies at lower energy than $^{2}T_{2a}$. The spin-orbit splitting of the $^{2}T_{2u}$ state which is not apparent in the absorption spectrum or solution MCD shows up strikingly in the crystal MCD illustrating the potentialities of crystal MCD studies, particularly at low temperatures. The MCD data show the expeted 1/T temperature dependence. en_US dc.format.extent 116416 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title MAGNETIC CIRCULAR DICHROISM OR $IrCl_{6}^{2-}$ IN CRYSTALLINE $(CH_{3}NH_{3})_{2}SnCl_{6}$ en_US dc.type article en_US
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