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dc.creatorPace, E. L.en_US
dc.date.accessioned2006-06-15T16:43:31Z
dc.date.available2006-06-15T16:43:31Z
dc.date.issued1968en_US
dc.identifier1968-D-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/15432
dc.descriptionAuthor Institution: Department of Chemistry, Case Western Reserve Universityen_US
dc.description.abstractInfrared spectra of the transformation of the $\alpha$-crystal of acetonitrile to the $\beta$-crystal observed at $-56.3^{\circ} C$ have been obtained. The multiplets arising from the resonance coupling in the $\alpha$- and $\beta$-crystal at $-165^{\circ} C$ have been characterized for three of the fundamental vibrations of the molecule: $\nu_{3}(A_{1})$, the symmetric methyl deformation mode; $\nu_{6}(E)$, the asymmetric methyl deformation mode; and $\nu_{7}(E)$, the asymmetric methyl wagging mode. Finally, the multiplets have been observed for the first time for the $\alpha$-crystal, the phase which is the thermodynamically stable at a low temperature.en_US
dc.format.extent96204 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleAN INFRARED INVESTIGATION OF THE $\alpha$ TO $\beta$ CRYSTAL TRANSITION IN ACETONITRILEen_US
dc.typearticleen_US


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