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dc.creatorDi Yorio, J. S.en_US
dc.creatorDurig, J. R.en_US
dc.date.accessioned2006-06-15T16:42:37Z
dc.date.available2006-06-15T16:42:37Z
dc.date.issued1967en_US
dc.identifier1967-X-8en_US
dc.identifier.urihttp://hdl.handle.net/1811/15397
dc.descriptionAuthor Institution: Department of Chemistry, University of South Carolinaen_US
dc.description.abstractThe infrared spectra of liquid and gaseous $CH_{3}OPCl_{2}$ and $CD_{3}OPCl_{2}$ have been measured from 4000 to $33 cm^{-1}$, and the Raman spectra of the liquids have been recorded and depolarization values have been measured. Methoxydichlorophosphine can have at most a plane of symmetry in which case it belongs to the point group C. The eighteen fundamental vibrations are divided into eleven of symmetry species $a^{\prime}$ and seven of $a^{\prime\prime}$ symmetry species. Nine fundamental vibrations result from the $CH_{3}$ motions and the assignments for these vibrations with the exception of the $CH_{3}$ torsion can be made by using previous assignments for the methyl group with $C_{3v}$ symmetry and the measured depolarization values. The remaining nine fundamental vibrations result from the motions of the $COPCl_{2}$ skeleton. These modes were found at $1036, 752, 506, 453, 403, 298, 218, 188$ and $124 cm^{-1}$ for the $CH_{2}OPCl_{2}$ molecule and at $1049, 716, 505, 456, 391, 294, 210, 187$ and $116 cm^{-1}$ for the deuterium compound. Assignment of these frequencies to the normal modes will be given. Existence of conformers and the values of barriers to internal rotation will be discussed.en_US
dc.format.extent151239 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleVIBRATIONAL SPECTRA AND STRUCTURE OF METHOXYDICHLORO-PHOSPHINE AND METHOXYDICHLOROPHOSPHINE-$d_{3}$.en_US
dc.typearticleen_US


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