Show simple item record

dc.creatorKing, Charles M.en_US
dc.creatorNixon, Eugene R.en_US
dc.date.accessioned2006-06-15T16:38:48Z
dc.date.available2006-06-15T16:38:48Z
dc.date.issued1967en_US
dc.identifier1967-K-9en_US
dc.identifier.urihttp://hdl.handle.net/1811/15274
dc.descriptionThis research was supported by ARPA Contract SD-69.en_US
dc.descriptionAuthor Institution: Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvaniaen_US
dc.description.abstractInfrared spectra of HCN and DCN in Ar, $N_{2}$ and CO matrices at $4^{\circ} K$ and $20^{\circ} K$ have been studied in the range from 4000-50 $cm^{-1}$. A detailed study of the effects of concentration and diffusion on the absorption bands of both isotopes are utilized to elucidate the structure of the various hydrogen-bonded aggregates. Both temperature and environment variations indicate that the dimer is probably linear or very nearly so and that the crystal field splits the degenerate modes of vibration. The results of calculations of hydrogen bond extensions, force constants, frequencies of lower lying vibrations, and hydrogen-bond energies of a variety of species in the $C-H\cdots N$ system using the Lippincott-Schroeder potential will be discussed.en_US
dc.format.extent120042 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMATRIX ISOLATION STUDIES OF HYDROGEN CYANIDE.en_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record