dc.creator King, Charles M. en_US dc.creator Nixon, Eugene R. en_US dc.date.accessioned 2006-06-15T16:38:48Z dc.date.available 2006-06-15T16:38:48Z dc.date.issued 1967 en_US dc.identifier 1967-K-9 en_US dc.identifier.uri http://hdl.handle.net/1811/15274 dc.description This research was supported by ARPA Contract SD-69. en_US dc.description Author Institution: Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania en_US dc.description.abstract Infrared spectra of HCN and DCN in Ar, $N_{2}$ and CO matrices at $4^{\circ} K$ and $20^{\circ} K$ have been studied in the range from 4000-50 $cm^{-1}$. A detailed study of the effects of concentration and diffusion on the absorption bands of both isotopes are utilized to elucidate the structure of the various hydrogen-bonded aggregates. Both temperature and environment variations indicate that the dimer is probably linear or very nearly so and that the crystal field splits the degenerate modes of vibration. The results of calculations of hydrogen bond extensions, force constants, frequencies of lower lying vibrations, and hydrogen-bond energies of a variety of species in the $C-H\cdots N$ system using the Lippincott-Schroeder potential will be discussed. en_US dc.format.extent 120042 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title MATRIX ISOLATION STUDIES OF HYDROGEN CYANIDE. en_US dc.type article en_US
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