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dc.creatorMcLeod, D., Jr.en_US
dc.creatorAngell, C. L.en_US
dc.date.accessioned2006-06-15T16:38:42Z
dc.date.available2006-06-15T16:38:42Z
dc.date.issued1967en_US
dc.identifier1967-K-6en_US
dc.identifier.urihttp://hdl.handle.net/1811/15271
dc.descriptionAuthor Institution: Union Carbide Research Instituteen_US
dc.description.abstractBenzyl radicals were prepared by the flash vacuum pyrolysis of benzyl bromide at $1000^{\circ}C$ and condensed with neon at $4^{\circ}K$. Spectra were obtained in the ultraviolet, visible and infrared regions. The (0,0) bands showed only very small shifts from their gas-phase values (e.g. $32,724 cm^{-1}$ in matrix, $32,745 cm^{-1}$ in gas). The following electronic transitions were observed $\begin{array}{ccc}Transition&(0,0) band\, in\, cm^{-1}&No.\, of\, vibrational\, bands\\ \qquad2\, ^{2}A_{2}\leftarrow 1\, ^{2}B_{2}&32,724&14\\ \qquad1\, ^{2}A_{2}\leftarrow 1\, ^{2}B_{2}&22,003&15\\ \qquad1\, ^{2}A_{2}\leftarrow 1\, ^{2}B_{2}&22,001&30\\ ({?})\quad 3\, ^{2}B_{2}\leftarrow 1\, ^{2}B_{2}&40,750&\qquad\qquad\qquad1 (very\, broad)\end{array}$ The infrared spectra showed the presence of the dimerization product bibenzyl. The correspondence between the infrared frequencies and the ground state vibrational frequencies obtained from the fluorescence spectra will be discussed.en_US
dc.format.extent123917 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleELECTRONIC AND INFRARED SPECTROSCOPY OF BENZYL RADICALS IN NEON MATRICES.en_US
dc.typearticleen_US


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