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dc.creatorShearer, S. J.en_US
dc.creatorTurrell, George C.en_US
dc.creatorBryant, James I.en_US
dc.creatorBrooks, R. L., IIIen_US
dc.date.accessioned2006-06-15T16:32:32Z
dc.date.available2006-06-15T16:32:32Z
dc.date.issued1966en_US
dc.identifier1966-K-2en_US
dc.identifier.urihttp://hdl.handle.net/1811/15049
dc.descriptionAuthor Institution: Howard University; Basic Research Laboratoryen_US
dc.description.abstractThe vibrational spectrum of cyanuric $(C_{3}N_{12})$ has been investigated in the crystalline state and in $CCl_{4}$ solutions. The selection rules for the infrared and Raman spectra of the crystalline azide (space group) $C^{2}_{6h})$ were determined by the ``unit cell'' method. The infrared spectrum was measured of samples in the form of sublimed film and in $CCl_{4}$ solutions over the frequency region from $200-4000 cm^{-1}$ using a Perkin-Elmer Model 621 Grating Spectrometer. Polarized Raman spectra were measured of $C_{2}N_{12}$ disk formed by the slow solidification of the molten salt and also of $C_{3}N_{12}$ in saturated solutions of $CCl_{4}$. The Raman spectrum of the solid was measured at 77 and $313^{\circ} K$. A Cary Model 81 Raman Spectrometer was used to investigate the Raman spectrum. Assignments were made for essentially all the $K\simeq 0$ modes distributed throughout the infrared and Raman spectra. The observed spectrum is in good agreement with the reported crystal structure, $C^{2}_{6h}$.en_US
dc.format.extent138336 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleVIBRATIONAL SPECTRUM OF CRYSTALLINE CYANURIC TRIAZIDEen_US
dc.typearticleen_US


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