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dc.creatorKittelberger, J. S.en_US
dc.creatorHornig, D. F.en_US
dc.date.accessioned2006-06-15T16:29:07Z
dc.date.available2006-06-15T16:29:07Z
dc.date.issued1965en_US
dc.identifier1965-V-9en_US
dc.identifier.urihttp://hdl.handle.net/1811/14923
dc.description$^{1}$ G. L. Hiebert, unpublished work. $^{2}$ P. A. Gigu\`{e}re and N. Zengin, Can. J. Chem. 36, 1013 (1958). $^{3}$ M. L. N. Sastri and D. F. Hornig. J. Chem. Phys. 39, 3497 (1963).en_US
dc.descriptionAuthor Institution: Frick Chemical Laboratory, Princeton Universityen_US
dc.description.abstractThe infrared spectra of films of solid HF and DF have been reinvestigated$^{1, 2, 3}$ and extended to cover the region $20-4000 cm^{-1}$. Previously unreported bands have been found in HF at $202 cm^{-1}$ and in DF at 210 and $358 cm^{-1}$, this latter being the analog of a transition in HF at $367 cm^{-1}$; from the isotope shifts, these are assigned as lattice translations. A pair of weak absorptions in the intramolecular region of DF corresponds to a similar pair in HF and these appear to be combinations of lattice translational and internal stretching modes. The Raman scattering from HF and DF crystals has been studied over the region $100-4000 cm^{-1}$; bands are detected in the intramolecular regions of both compounds. Simple vector and tensor intensity calculations are used to aid the assignment of vibrational transitions. The spectra are discussed in terms of a four-molecule, $D_{2b}$ unit cell, and the effects of various kinds of disorder are considered.en_US
dc.format.extent154376 bytes
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dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE VIBRATIONAL SPECTRUM OF CRYSTALLINE HYDROGEN FLUORIDE.en_US
dc.typearticleen_US


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