HIGHER ORDER CENTRIFUGAL DISTORTION EFFECTS IN ASYMMETRIC ROTATORS.
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Publisher:Ohio State University
A survey will be given of the asymmetric rotator centrifugal distortion constants which are associated with the sixth-power angular-momentum-component terms of the vibration-rotation Hamiltonian. For the case of most immediate experimental interest, viz., that of the non-linear XYX triatomic molecule, the centrifugal distortion constants have been calculated explicitly in terms of the fundamental molecular structure constants. The Nielsen-Amat expansion of the vibration-rotation Hamiltonian was used for this calculation.
Author Institution: Department of Physics, Michigan State University; Department of Physics, University of South Florida
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