dc.creator Kennealy, J. P. en_US dc.creator Stair, A. T., Jr. en_US dc.date.accessioned 2006-06-15T16:24:46Z dc.date.available 2006-06-15T16:24:46Z dc.date.issued 1965 en_US dc.identifier 1965-B-4 en_US dc.identifier.uri http://hdl.handle.net/1811/14755 dc.description Author Institution: Concord Radiance Laboratory Utah State University, Bedford, Massachusetts; Air Force Cambridge Research Laboratories (O.A.R.), L.G. Hanscom Field. Bedford, Massachusetts, 01731. en_US dc.description.abstract Infrared emission from the low-pressure gas-phase NO-O reaction system has been studied from 1 to 6.5 microns. An infrared integrating sphere has been used for the reaction cell to provide increased light-gathering efficiency, and because of the relatively weak source, the emission spectra were observed with an interferometer spectrometer. Spectra obtained indicate that the continuum'' associated with the NO-O recombination extends to at least 4 microns. Vibrational emissions from $NO, NO_{2}$, and $N_{2}O$ have been observed and their relative intensities studied versus concentrations of the reactants. Several weaker bands have also been observed, but are presently unidentified. The intensity of the vibrational emission relative to the continuum radiation has been found to be pressure-dependent due to the considerably different radiative and collision lifetimes involved. Infrared emission spectroscopy may be able to contribute much to the study of chemical kinetics. dc.format.extent 134187 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title INFRARED CHEMILUMINESCENCE FROM THE NO-O REACTION SYSTEM STUDIED BY FOURIER SPECTROSCOPY dc.type article en_US
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