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dc.creatorKennealy, J. P.en_US
dc.creatorStair, A. T., Jr.en_US
dc.date.accessioned2006-06-15T16:24:46Z
dc.date.available2006-06-15T16:24:46Z
dc.date.issued1965en_US
dc.identifier1965-B-4en_US
dc.identifier.urihttp://hdl.handle.net/1811/14755
dc.descriptionAuthor Institution: Concord Radiance Laboratory Utah State University, Bedford, Massachusetts; Air Force Cambridge Research Laboratories (O.A.R.), L.G. Hanscom Field. Bedford, Massachusetts, 01731.en_US
dc.description.abstractInfrared emission from the low-pressure gas-phase NO-O reaction system has been studied from 1 to 6.5 microns. An infrared integrating sphere has been used for the reaction cell to provide increased light-gathering efficiency, and because of the relatively weak source, the emission spectra were observed with an interferometer spectrometer. Spectra obtained indicate that the ``continuum'' associated with the NO-O recombination extends to at least 4 microns. Vibrational emissions from $NO, NO_{2}$, and $N_{2}O$ have been observed and their relative intensities studied versus concentrations of the reactants. Several weaker bands have also been observed, but are presently unidentified. The intensity of the vibrational emission relative to the continuum radiation has been found to be pressure-dependent due to the considerably different radiative and collision lifetimes involved. Infrared emission spectroscopy may be able to contribute much to the study of chemical kinetics.
dc.format.extent134187 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED CHEMILUMINESCENCE FROM THE NO-O REACTION SYSTEM STUDIED BY FOURIER SPECTROSCOPYen_US
dc.typearticleen_US


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