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dc.creatorUy, Daireneen_US
dc.creatorWhite, E. T.en_US
dc.creatorOka, T.en_US
dc.date.accessioned2006-06-15T15:29:55Z
dc.date.available2006-06-15T15:29:55Z
dc.date.issued1996en_US
dc.identifier1996-MG-06en_US
dc.identifier.urihttp://hdl.handle.net/1811/13458
dc.description$^{1}$Verhoeve, p., et al. Chem. Phys. Lett. 161, 195, 1989.en_US
dc.descriptionAuthor Institution: Department of Chemistry and Department of Astronomy and Astrophysics, The University of Chicagoen_US
dc.description.abstractAlthough the vibration-rotation spectrum of $H_{3}O^{+}$ has been studied extensively, there has been no experimental information on the value of the C rotational constant because of the absensce of $\Delta|k-l|\neq 0$ forbidden transitions. There is a near degeneracy between the (9,0)$^{+}$ and the (9,3)$^{-}$ ground state rotation-inversion levels, as pointed out by Verhoeve, $et al.^{1}$ Indeed the ground state combination differences of the $v_{3}$ fundamental transitions show a sizable shift of the (9.3)$^{-}$ level as well as the neighboring (7,3)$^{-}$ and (11,3)$^{-}$ levels. We have obtained 11 forbidden $v_{3}$ transitions involving these ground state levels. This enabled us to determine the energy difference between different K levels and the mixing coefficient $\tau_{xxxz}$. An extended analysis of the $v_{3}$ bands is in progress.en_US
dc.format.extent75209 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleOBSERVATION OF $\Delta|k-l|-3$ TRANSITIONS IN THE $v_{3}$ BAND OF $H_{3}O^{+}$en_US
dc.typearticleen_US


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