Large Amplitude Motions of Molecules and Ions Revealed by Supersonic Jet Spectroscopy
Publisher:
Ohio State UniversityAbstract:
Several laser electronic spectroscopies are applied for the study of large amplitude motions of aromatic molecules and ions in supersonic jets. The internal rotation of the $CH_{3}$ group in substituted toluenes in ground, excited and ionic states is mainly discussed. Large-amplitude ``butterfly tunneling” motion in 1,2,4,5-tetrafluorobenzene is also described.
Description:
Author Institution: Institute for Molecular Science
Type:
articleOther Identifiers:
1994-MA-02Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.