dc.creator Byers, Teresa J. en_US dc.creator Kerr, Karen E. en_US dc.creator Weliky, David P. en_US dc.creator Momose, Takamasa en_US dc.creator Oka, T. en_US dc.date.accessioned 2006-06-15T15:14:03Z dc.date.available 2006-06-15T15:14:03Z dc.date.issued 1992 en_US dc.identifier 1992-RG-04 en_US dc.identifier.uri http://hdl.handle.net/1811/12809 dc.description 1. J. Van Kranendonk, Solid Hydrogen. 1983 Plenum Press, New York 2. V.F. Sears and J. Van Kranendonk, Canadian Journal of Physics, {\bf 42} , 980 (1964) en_US dc.description Author Institution: Department of Chemistry and Department Astronomy and Astrophysics, The University of Chicago en_US dc.description.abstract High resolution infrared studies of the Q1(0) vibrational transition of D2 impurity in a solid hydrogen matrix and of the rovibrational $W_{1}(0)$ transition in solid $H_{2}$ have revealed a multitude of interesting features, the precise interpretation of which requires the refinement of existing theory.$^{1}$ Analysis of the $Q_{1}$(0) spectrum of $D_{2}$ is based on the J=1 quadrupole-induced dipole moment mechanism analogous to that used for the Q-branch of $H_{2}2^{2}$ Fine structure is interpreted on the basis of a calculation of the crystal field of the J=1 impurity in the presence of a neighboring J=0 $D_{2}$ molecule. The $W_{1}$(0) main feature is accompanied by a large number of satellites due to coupling of the J=6 excitation with J=1 impurities in the lattice. We discuss the fit of the spectrum based on axially symmetric interactions of the J=6/J=1 pair as well as non-axially symmetric interactions resulting from the crystal environment. en_US dc.format.extent 108407 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title ON THE THEORY OF INTERMOLECULAR AND CRYSTAL FIELD INTERACTIONS IN SOLID HYDROGEN en_US dc.type article en_US
﻿