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dc.creatorMeier, V. A.en_US
dc.creatorMcDermott, D. P.en_US
dc.date.accessioned2006-06-15T15:06:38Z
dc.date.available2006-06-15T15:06:38Z
dc.date.issued1991en_US
dc.identifier1991-TC-14en_US
dc.identifier.urihttp://hdl.handle.net/1811/12513
dc.description$^{1}$E. Frasson, E. Menegus and C. Panattoni, Nature, 199, 1087 (1963).""en_US
dc.descriptionAuthor Institution: New Jersey Medical College; Division of Science and Math, Lees College, Jacksonen_US
dc.description.abstractComplete vibrational analyses of Cyclopentadienyl (CPDA) thallium have been performed resulting in two different simple valence force fields. One force field was obtained from a fit to MOPAC/MINDO generated vibrational frequencies. The other force field is a set of true empirical force constants obtained from fitting to IR and Raman-observed frequencies. Comparison of the two force fields shows them to be remarkably similar. The Raman spectrum of CPDA thallium is interesting and singular because it has unusually narrow and sharp CC stretching bands which have only been observed before in IR spectra of CPDA-metal compounds. Although CPDA-thallium is believed to be a simple ionic salt in the solid $phase^{1}$, explanation of the Raman spectrum can be provided only through the assumption of a sandwich compound to some extent in the solid phase.en_US
dc.format.extent83570 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED AND RAMAN SPECTRA AND VIBRATIONAL ANALYSES OF CYCLOPENTADIENYL THALLIUMen_US
dc.typearticleen_US


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