MICROWAVE SPECTRA OF TRANS-1, 2-DIFLUOROETHYLENE OXIDE
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Publisher:Ohio State University
The microwave spectra of trans-1, 2-difluoroethylene oxide was investigated in the region of 26.5 to 40 GHz. A fit of the near-prolate $\mu b$-type spectrum gave the following rotational constants (MHz) for the ground state normal isotope: $A = 14731.47, B = 3582.85$ and $C= 3222.44$. The electric dipole moment was measured to be $\mu b = \mu T = 1.110$. The dideutero species, CDFCDFO, and the oxygen-18 species, CHFCHF180, have been assigned and presently work is in progress on the carbon-13 isotopic assignment. The isotopic data will be used to discuss the molecular structure.
Author Institution: Department of Chemistry, Rensselaer Polytechnic Institute Troy; Department of Chemistry, Charles Stark Draper Laboratory
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