dc.creator David, Shelle J. en_US dc.creator Ault, Bruce S. en_US dc.date.accessioned 2006-06-15T14:49:03Z dc.date.available 2006-06-15T14:49:03Z dc.date.issued 1983 en_US dc.identifier 1983-RH-03 en_US dc.identifier.uri http://hdl.handle.net/1811/11927 dc.description Author Institution: Department of Chemistry, University of Cincinnati en_US dc.description.abstract The oxide salt/molecule reaction technique was recently developed for the formation of oxyanions in matrices, through the transfer of $O^{2-}$ from $Tl_{2}O$ to a suitable acceptor. The reaction of $Tl_{2}O$ with Ar/$SO_{2}$ produced a number of product bands. Moreover, the concentration and temperature dependence of the product bands suggested that more than one species was formed. The first set of bands has been assigned to the $SO_{3}^{2-}$ anion with an effective symmetry of less than $C_{3y}$ due to ion pairing. The second series of product bands has been assigned to the symmetrical $O_{2}SOSO^{2-}_{2}$ structure for the disulfite ion. This technique is currently being applied to the reaction of $Tl_{2}O$ with $BF_{3}$ in inert matrices. To date, no assignments have been made for the product species. en_US dc.format.extent 79937 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title INFRARED MATRIX ISOLATION STUDIES OF REACTIVE OXYANIONS en_US dc.type article en_US
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