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dc.creatorFreedman, T. B.en_US
dc.creatorZimba, C. G.en_US
dc.creatorZuk, W.en_US
dc.creatorNafie, L. A.en_US
dc.date.accessioned2006-06-15T14:47:37Z
dc.date.available2006-06-15T14:47:37Z
dc.date.issued1983en_US
dc.identifier1983-RC-03en_US
dc.identifier.urihttp://hdl.handle.net/1811/11876
dc.descriptionAuthor Institution: Department of Chemistry, Syracuse Universityen_US
dc.description.abstractThe normal modes giving rise to the Raman optical activity (ROA) spectrum of (+)-(3R)-methylcyclohexanone in the region below $650 cm^{-1}$ have been assigned based on Raman spectra of the parent compound and five specifically deuterated isotopomers. Stereoprojections of the molecule displaced along the vibrational coordinates demonstrate that the low frequency normal modes and ROA fetures arise from deformation and torsional modes of the cyclohexane $C_{6} (D_{3d})$ skeleton coupled to axial and equitorial motion of the carbonyl and methyl groups, and an additional methyl torsional mode. Calculations of ROA intensity using the Raman atomic polar tensor $model^{1}$ will be presented and compared to experiment. $^{1}$T. B. Freedman and L. A. Nafie, J. Chem. Phys. 78, 27 (1983).en_US
dc.format.extent77314 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleRAMAN OPTICAL ACTIVITY IN THE SKELETAL MOTIONS OF (+)-(3R)-METHYLCYCLOHEXANONEen_US
dc.typearticleen_US


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