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dc.creatorKalasinsky, V. F.en_US
dc.creatorPool, J. L.en_US
dc.creatorYeh, Y. Y.en_US
dc.creatorWurrey, C. J.en_US
dc.date.accessioned2006-06-15T14:47:10Z
dc.date.available2006-06-15T14:47:10Z
dc.date.issued1983en_US
dc.identifier1983-MH-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/11859
dc.descriptionAuthor Institution: Department of Chemistry, Mississippi state University Mississippi state; Department of Chemistry, University of Missouri Kansas City; Department of Chemistry, University of California --San Diegoen_US
dc.description.abstractThe infrared and Raman spectra of (cyanomethyl)cyclopropane and dicyclopropylmethane have been studied. Each molecule exhibits a conformational equilibrium in the fluid states while a single conformer exists in the crystalline solid state. Two sets of doublets exist in the Raman spectrum of liquid (cyanomethyl) cyclopropane and the temperature dependence of the line intensities is consistent with an energy difference of $0.70\pm$ 0.10 Kcal/mole with the gauche conformer more stable than the cis. In dicyclopropylmethane, at least two conformers exist in the liquid state, and these have been identified as gauche-gauche conformers exhibiting $C_{2}$ and $C_{8}$ molecular symmetries. The former was determined to be $0.93 \pm 0.10$ kcal/mole more stable than the latter. Comparisons with similar molecules and a discussion of the conformer equilibria will be given.en_US
dc.format.extent85844 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleVIBRATIONAL SPECTRA AND CONFORMATIONS OF (CYANOMETHYL)CYCLOPROPANE AND DICYCLOPROPYLMETHANEen_US
dc.typearticleen_US


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