SPLITTING OF DEGENERACY OF THE BENZENE: RADICAL CATION GROUND STATE BY ASYMMETRIC SUBSTITUTIONS
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Ohio State UniversityAbstract:
Various Substituted benzene cations were studied by time, wavelength, and polarization resolved laser induced flourescence in solid No matrices. The polarization behaviour identifies unambiguously emission bands belonging to the $B\rightarrow A$ electronic transition. The ground state vibrational structure and vibronic interactions with the low lying A state are examined.
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