dc.creator Michelot, F. en_US dc.date.accessioned 2006-06-15T14:36:59Z dc.date.available 2006-06-15T14:36:59Z dc.date.issued 1980 en_US dc.identifier 1980-WF-16 en_US dc.identifier.uri http://hdl.handle.net/1811/11453 dc.description $^{1}$ R.E. Moss, 1973, Advanced Molecular Quantum Mechanics, Chapman and Hall Ltd London. B.J. Howard and R.E. Moss, Molecular Physic 19, 433-450 (1970) en_US dc.description Author Institution: en_US dc.description.abstract A new approach to the study of such effects is proposed on the basis of the molecular hamiltonian developed by R. E. MOSS (1). At first this hamiltonian is completed to include all relevant interaction terms involving nuclear magnetic moments. The transformation from space-fixed coordinates to molecular ones is performed directly and the effective Hamiltonian for a ground electronic $^{1}\Sigma$ state is calculated to second order in degenerate perturbation theory. We thus obtain explicitly all dominant parameters for the spin-vibration and spin-rotation interactions together with those associated with the interactions between the magnetic moment induced by molecular motion with an external magnetic field. The hamiltonian is then written in a form adapted to the obtention of an effective Hamiltonian for an arbitrary vibrational state. en_US dc.format.extent 121057 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title NUCLEAR HYPERFINE INTERACTIONS IN NON-LINEAR MOLECULES IN $^{1}\Sigma$ STATES: A STUDY OF EFFECTS INDUCED BY MOLECULAR VIBRATION en_US dc.type article en_US
﻿