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dc.creatorBaiocchi, F. A.en_US
dc.creatorDixon, T. A.en_US
dc.creatorJoyner, C. H.en_US
dc.creatorKlemperer, Williamen_US
dc.date.accessioned2006-06-15T14:35:44Z
dc.date.available2006-06-15T14:35:44Z
dc.date.issued1980en_US
dc.identifier1980-TF-3en_US
dc.identifier.urihttp://hdl.handle.net/1811/11400
dc.descriptionAuthor Institution:en_US
dc.description.abstractThe molecular beam electric resonance technique was used to obtain rotational spectra of $CO_{2}-HF$ a weakly bound species formed by nozzle expansion of an HF, $CO_{2}$, and Ar mixture. The spectroscopic results indicate that the $CO_{2}-HF$ system is nearly linear, and furthermore, study of the $CO_{2}-DF$ system shows that the hydrogen points towards the $CO_{2}$ unit. The spectroscopic constants are used to determine two structural parameters in each system: r, the distance between the centers of mass of the a-axis of the molecule, and $<\cos^{2}\theta>$, where $\theta$ is the angle between the HF unit and the a-axis of the molecule. The latter quantity is determined from (eqQ)$_{D}$, for $CO_{2}-DF$, and from $S_{HF}$, the spin-spin coupling constant, for $CO_{2}-HF$. Finally, the centrifugal distortion constant D is related to the strength of the weak bond. The molecular constants are :[FIGURE]en_US
dc.format.extent121384 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSTRUCTURE DETERMINATION OF $CO_{2}-HF$ BY MOLECULAR BEAM ELECTRIC RESONANCE SPECTROSCOPYen_US
dc.typearticleen_US


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