dc.creator Lowe, R. S. en_US dc.creator McKellar, A. R. W. en_US dc.date.accessioned 2006-06-15T14:33:06Z dc.date.available 2006-06-15T14:33:06Z dc.date.issued 1980 en_US dc.identifier 1980-RF-8 en_US dc.identifier.uri http://hdl.handle.net/1811/11302 dc.description Author Institution: en_US dc.description.abstract Using the technique of intracavity laser magnetic resonance we have observed and analysed over 200 resonances from the CD stretching vibration $\nu_{1}$ of the deuterated formyl radical, DCO. Analysis of these transitions has provided accurate determinations of the band origin, rotational, centrifugal distortion and spin rotation parameters for the $\nu_{1} =1$ vibrational state. In addition, by incorporating into the analysis the effects of Coriolis interaction between $\nu_{1}$ and $\nu_{3}$ we were able to determine the Coriolis coupling constant and some effective $\nu_{3}$ band parameters. These parameters subsequently led to the assignment of some weak lines to $\nu_{3}$ band transitions. The vibrational band origins were found to be; for (100), $\nu_{0} = 1909.773$ $cm^{-1}$; for (001), $\nu_{0} = 1794.613$ $cm^{-1}$. en_US dc.format.extent 98634 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title LASER MAGNETIC RESONANCE SPECTROSCOPY OF THE $\nu_{1}$ AND $\nu_{3}$ VIBRATIONAL FUNDAMENTALS OF DCO en_US dc.type article en_US
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