Show simple item record

dc.creatorLowe, R. S.en_US
dc.creatorMcKellar, A. R. W.en_US
dc.date.accessioned2006-06-15T14:33:06Z
dc.date.available2006-06-15T14:33:06Z
dc.date.issued1980en_US
dc.identifier1980-RF-8en_US
dc.identifier.urihttp://hdl.handle.net/1811/11302
dc.descriptionAuthor Institution:en_US
dc.description.abstractUsing the technique of intracavity laser magnetic resonance we have observed and analysed over 200 resonances from the CD stretching vibration $\nu_{1}$ of the deuterated formyl radical, DCO. Analysis of these transitions has provided accurate determinations of the band origin, rotational, centrifugal distortion and spin rotation parameters for the $\nu_{1} =1$ vibrational state. In addition, by incorporating into the analysis the effects of Coriolis interaction between $\nu_{1}$ and $\nu_{3}$ we were able to determine the Coriolis coupling constant and some effective $\nu_{3}$ band parameters. These parameters subsequently led to the assignment of some weak lines to $\nu_{3}$ band transitions. The vibrational band origins were found to be; for (100), $\nu_{0} = 1909.773$ $cm^{-1}$; for (001), $\nu_{0} = 1794.613$ $cm^{-1}$.en_US
dc.format.extent98634 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleLASER MAGNETIC RESONANCE SPECTROSCOPY OF THE $\nu_{1}$ AND $\nu_{3}$ VIBRATIONAL FUNDAMENTALS OF DCOen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record