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dc.creatorDwarakanath, K.en_US
dc.creatorSmith, R. V.en_US
dc.creatorPrasad, Paras N.en_US
dc.date.accessioned2006-06-15T14:18:04Z
dc.date.available2006-06-15T14:18:04Z
dc.date.issued1979en_US
dc.identifier1979-TH-12en_US
dc.identifier.urihttp://hdl.handle.net/1811/11070
dc.description$^{1}$C.N. Sukenik, J.A.P. Bonapace, N.S. Mandel, P,.V. Lau, G. Wood and R.G. Bergman, J. Am. Chem. Soc, 99, 851 (1977). $^{*}$Alfred P. Sloan Fellowen_US
dc.descriptionAuthor Institution:en_US
dc.description.abstractMethyl-p-dimethyl aminobenzenesul fonate (MSE), a stable compound in solution, slowly undergoes a rearrangement in the solid state into p-trimethylammoniumbenzenesulfonate zwetterion $(ZWT)^{1}$. The rate of this lattice controlled reaction can be thermally enhanced. This paper presents a laser Raman spectroscopic investigation of the solid state rearrangement of MSE into ZWT. Both the phonon spectra and the internal vibration spectra of single crystals of MSE and $MSE-d^{3}$ are studied as a function of percentage conversion to examine the mechanism of the reaction, the nature of the lattice rearrangement and the role of methyl group motions. ACKNOWLEDGMENT This research was supported by Air Office of Scientific Research Grant \#AFOSR 78-3676.en_US
dc.format.extent93386 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleLASER RAMAN STUDY OF THE THERMAL REARRANGEMENT OF METHYL P-DIMETHYLAMINOBENZENESULFONATE IN SOLID STATEen_US
dc.typearticleen_US


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