Show simple item record

dc.creatorAlderdice, D. S.en_US
dc.creatorLanini, K. P.en_US
dc.creatorZimmerman, R.en_US
dc.creatorDunn, T. M.en_US
dc.date.accessioned2006-06-15T14:13:11Z
dc.date.available2006-06-15T14:13:11Z
dc.date.issued1979en_US
dc.identifier1979-RE-03en_US
dc.identifier.urihttp://hdl.handle.net/1811/10901
dc.description$^{1}$ T.M. Dunn and A.H. Francis, J. Mol. Spectrosc. 25, 86 (1968). $^{2}$ R. N. Dixon and C.R. Webster, J. Mol. Spectrosc. 62, 271 (1976). $^{3}$ J. A. Blazy and D. H. Levy, J. Chem. Phys. 69, 2901 (1978).en_US
dc.descriptionAuthor Institution:en_US
dc.description.abstractThe electronic absorption spectrum of chromyl chloride vapor reveals substantial vibrational and rotational structure based on electronic $origin^{1}$ at 5800$\AA$. Five progressions are observed, each with a progression interval of 136$cm^{-1}$. Although a single vibronic level fluorescence study of the vapor at room $temperature^{2}$ and a fluorescence excitation spectrum of $CrO_{2}Cl_{2}$ cooled in a free jet $expansion^{3}$ have been published, the vibrational and rotational analyses of this system are incomplete. High resolution ($0.03 cm^{-1}$)room temperature absorption spectra of isotopically pure $CrO_{2}^{35}Cl_{2}$ have provided detailed rotational contours at high J of many members of each progression, permitting assignments of the vibronic symmetries of the bands. Isotopic splittings, determined from measurements of similar spectra of samples with a natural abundance of Cl isotopes, have also been obtained. From this information a more complete vibrational analysis of the system has been carried out.en_US
dc.format.extent99616 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleANALYSIS OF THE 5800{\AA} SYSTEM OF CHROMYL CHLORIDE $(Cro_{2}Cl_{2})$ IN THE VAPOR PHASEen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record