NORMAL COORDINATE TREATMENT OF TETRACHLOROCYCLOPROPENE
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Publisher:Ohio State University
Fundamental frequencies from recent infrared and Raman spectroscopic studies and mean square amplitudes of vibration from electron diffraction data have been employed in a normal coordinate calculation for tetrachlorocyclopropene. A comparison of these results with those of a similar study for cyclopropene has been made to inves tigate the effects of substituents of considerable mass and polarizability on the potential field of a highly strained ring system, Raman intensity measurements and polarizability derivatives will also be presented.
Author Institution: Department of Physics, Southern Methodist University; Department of Chemistry, North Texas State University
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