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dc.creatorGill, R. J.en_US
dc.creatorAtkinson, G. H.en_US
dc.description$^{1}$N. C. Peterson, K. J, Kurylo, W, Braum, A. M. Bass, and R. A. Keller, J. Opt. Soc, Am. 61, 746 (1971). $^{2}$T. W. Hansch, A. L. Schlawlow, and P. E. Toschek, IEEE J. Quant. Electronics QE-8, 802 (1972). $^{3}$G, H. Atkinson, A. H. Laufer, and M, J. Kurylo, J. Chem. Phys. 59, 350 (1973). $^{4}$G. H. Atkinson, T. N. Heimlich, and M. W. Schuyler, J. Chem, Phys. 66, 5005 (1977). This work was supported by the NSF and the American Chemical Society.""en_US
dc.descriptionAuthor Institution: Department of Chemistry, Syracuse Universityen_US
dc.description.abstractThe large $(10^{3}$ to $10^{5}$) enhancements in detection sensitivity achievable with intracavity laser detection (ILD)$^{1,2,3}$ has made it feasible to observe the spectroscopy of gas phase radicals within 50 nsec of their production from the dissociation of parent polyatomics. Instrumentation utilizing a cw dye laser and optical multichannel detection will be described. ILD is used to obtain $quantitative^{4}$ information on the energetic onsets in the photolysis of the parent for radical production, reaction rates of radical species, and the time-dependent internal energy content of radicals following production. Results for HCO production from carbonyl molecules, will be presented to Illustrate these types of data.en_US
dc.format.extent138164 bytes
dc.publisherOhio State Universityen_US

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