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dc.creatorRussell, B. R.en_US
dc.creatorCausley, G. C.en_US
dc.date.accessioned2006-06-15T14:04:32Z
dc.date.available2006-06-15T14:04:32Z
dc.date.issued1978en_US
dc.identifier1978-RD-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/10497
dc.descriptionAuthor Institution: Department of Chemistry, North Texas State Universityen_US
dc.description.abstractThe initial, studies of electric field effects on the absorptions that result from excitations to molecular Rydberg states indicated a large delocalization of electronic charge. This work was completed using a technique known as ``electrochromism^{\prime\prime}, which is the differential absorption of a molecule that results from uniform electric field being applied to an otherwise randomly oriented sample. Recently, to gain greater insight into these electric field effects, a system was built where the sample is oriented and then probed with light polarized at $0^{\circ}$, then $90^{\circ}$, with respect to the applied field (i.e. electric linear dichroism). This new technique has been employed in conjunction with electro-chromism. These combined results allow the determination of a number of excited state parameters including excited dipole moment excited state polarizability and polarization of transition, moment with respect to the ground state permanent dipole moment. The technique also affords the evaluation of the angular shift of excited dipole moment with respect to ground state moment. The results which have been obtained to date regarding current ongoing investigations of molecular Rydberg states will be presented.en_US
dc.format.extent147375 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleELECTRIC LINEAR DICHROISM SPECTRA OF MOLECULAR RYDBERG TRANSITIONSen_US
dc.typearticleen_US


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