# FAR-INFRARED SPECTRA AND RING-PUCKERING VIBRATION OF 1,3-DISILACYCLOBUTANE –$d_{0}$ AND -$d_{4}$

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 Title: FAR-INFRARED SPECTRA AND RING-PUCKERING VIBRATION OF 1,3-DISILACYCLOBUTANE –$d_{0}$ AND -$d_{4}$ Creators: Irwin, R. M.; Laane, J. Issue Date: 1975 Publisher: Ohio State University Abstract: The far infrared spectra of $H_{2}SiSH_{2}CH_{2}$ and its $d_{4}$ analog have been recorded in the $20-100 cm^{-1}$ region. A large number of bands corresponding to the puckering mode were observed for each compound. The data are correlated with infrared combination bands and low-frequency Raman lines in order to obtain the potential energy function. A barrier of inversion of $88 cm^{-1}$ was determined. Description: This work was supported by the Robert A. Welch Foundation. Author Institution: Department of Chemistry, Texas A\&M University URI: http://hdl.handle.net/1811/9527 Other Identifiers: 1975-WE-10