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THE MICROWAVE AND MATRIX INFRARED SPECTRUM OF PEROXYACETIC ACID ($CH_{3}-O_{=_{O}}-OOH$)

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/9488

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dc.creator Cugley, J. A. en_US
dc.creator Bauder, A. en_US
dc.creator Günthard, Hs. H. en_US
dc.date.accessioned 2006-06-15T13:41:50Z
dc.date.available 2006-06-15T13:41:50Z
dc.date.issued 1975 en_US
dc.identifier 1975-TF-13 en_US
dc.identifier.uri http://hdl.handle.net/1811/9488
dc.description Author Institution: Laboratory for Physical Chemistry, ETH, Universit\""{a}tstrasse 22"" en_US
dc.description.abstract Peroxyacetic acid is an interesting molelcule because it can be prepared chemically via ozonolysis from many different starting products, and hence is of some interest in atmospheric pollution--particularly so, because it is a strong oxidizing agent. Spectroscopically, one can imagine torsional motion about the C-O and O-O bonds as well as methyl torsion, and consequently the microwave spectrum is expected to be very rich and, indeed, this is the case. Other questions to be answered are the planarity of the peroxy group, and the vibrational assignment of the modes associated with the strong internal hydrogen bond. en_US
dc.format.extent 99731 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title THE MICROWAVE AND MATRIX INFRARED SPECTRUM OF PEROXYACETIC ACID ($CH_{3}-O_{=_{O}}-OOH$) en_US
dc.type article en_US