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THE EMISSION SPECTRUM OF $HCl^{+}:$ RECENT OBSERVATIONS OF THE 3500 {\AA} SYSTEM

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/8925

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dc.creator Sheasley, W. David en_US
dc.creator Mathews, C. W. en_US
dc.date.accessioned 2006-06-15T13:29:35Z
dc.date.available 2006-06-15T13:29:35Z
dc.date.issued 1972 en_US
dc.identifier 1972-C-10 en_US
dc.identifier.uri http://hdl.handle.net/1811/8925
dc.description $^{1}$F. Norling, Z. Phys. 104. 638 (1937); 106, 177 (1937). $^{2}$L. Marsigny and J. Ferran, C.R. Acad. Sci. 262C, 531 (1966)."" en_US
dc.description Author Institution: Department of Chemistry, The Ohio State University en_US
dc.description.abstract The electronic spectra of $HCl^{+}$ and $DCl^{+}$ have been obtained in emission from an electrodeless discharge excited by microwave radiation. Previous $observations^{1,2}$ have been extended to include many additional bands involving higher vibrational levels in both the ground $(X^{2}\Pi_{i})$ and excited $(A^{2}\Sigma^{+})$ electronic states, leading to much improved values of equilibrium constants and dissociation energies. The work includes the first analysis of the system for the $Cl-37$ isotope. For each isotopic molecule, combination differences taken from at least seven bands were used to determine term values for the $v^{\prime}^{\prime}=O$ vibrational level. These were used along with observed transitions to obtain term values for all other observable energy levels in both electronic states. This procedure has provided the most efficient use of the more than 10 000 lines that have been assigned. en_US
dc.format.extent 121434 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title THE EMISSION SPECTRUM OF $HCl^{+}:$ RECENT OBSERVATIONS OF THE 3500 {\AA} SYSTEM en_US
dc.type article en_US