VIBRATIONAL SPECTRA OF THE $LiClO_{4}$ MONOMER, GLASS, LIQUID AND CRYSTAL

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 Title: VIBRATIONAL SPECTRA OF THE $LiClO_{4}$ MONOMER, GLASS, LIQUID AND CRYSTAL Creators: Smyrl, Norman; Li, P. C.; Devlin, J. Paul Issue Date: 1972 Publisher: Ohio State University Abstract: Volatilization of $LiClO_{4}$ permits the vapor deposition of the glass phase as well as matrix isolation of monomeric $LiClO_{4}$. The strong distortion of the tetrahedral $ClO_{4}$ anion in the 1:1 association with lithium can be viewed as a limiting case and, thus, is informative regarding cation-anion interactions in other media, such as molten salt systems. The monomer and glass spectra will be contrasted with data for the melt and crystal phases. Description: Author Institution: Department of Chemistry, Oklahoma State University URI: http://hdl.handle.net/1811/8914 Other Identifiers: 1972-BB-10