l-TYPE RESONANCE IN THE $v_{5}+v_{10}$ BAND OF CYCLOPROPANE

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 dc.creator Maki, A. G. en_US dc.date.accessioned 2006-06-15T13:24:19Z dc.date.available 2006-06-15T13:24:19Z dc.date.issued 1971 en_US dc.identifier 1971-G-11 en_US dc.identifier.uri http://hdl.handle.net/1811/8678 dc.description $^{1}$G. J. Cartwright and I. M. Mills. J. Mol. Spectrosc. 34, 415 (1970)."" en_US dc.description Author Institution: National Bureau of Standards en_US dc.description.abstract The $v_{5}+ v_{10}$ band of cyclopropane centered at $2089.52 cm^{-1}$ has been measured and analyzed taking into account the l-type resonance effect described by Cartwright and $Mills.^{1}$ The J-structure of five Q-branches of this band were resolved and the $^{P} P$ and $^{R}$R-transitions were identified up to J = 25 and K = 25. A least squares fit of more than 300 well resolved transitions gave a set of band constants which reproduced the measurements with a standard deviation of $0.003 cm^{-1}$. The analysis confirms the l-type resonance treatment given by Cartwright and Mills and shows that their band contour fit gave remarkably accurate constants for this band. The 2$v_{10}$(E) band has also been observed at $2054.5 cm^{-1}$. en_US dc.format.extent 92328 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.title l-TYPE RESONANCE IN THE $v_{5}+v_{10}$ BAND OF CYCLOPROPANE en_US dc.type article en_US