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l-TYPE RESONANCE IN THE $v_{5}+v_{10}$ BAND OF CYCLOPROPANE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/8678

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Title: l-TYPE RESONANCE IN THE $v_{5}+v_{10}$ BAND OF CYCLOPROPANE
Creators: Maki, A. G.
Issue Date: 1971
Abstract: The $v_{5}+ v_{10}$ band of cyclopropane centered at $2089.52 cm^{-1}$ has been measured and analyzed taking into account the l-type resonance effect described by Cartwright and $Mills.^{1}$ The J-structure of five Q-branches of this band were resolved and the $^{P} P$ and $^{R}$R-transitions were identified up to J = 25 and K = 25. A least squares fit of more than 300 well resolved transitions gave a set of band constants which reproduced the measurements with a standard deviation of $0.003 cm^{-1}$. The analysis confirms the l-type resonance treatment given by Cartwright and Mills and shows that their band contour fit gave remarkably accurate constants for this band. The 2$v_{10}$(E) band has also been observed at $2054.5 cm^{-1}$.
URI: http://hdl.handle.net/1811/8678
Other Identifiers: 1971-G-11
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