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SOLID STATE ELECTRONIC SPECTRA OF RETENOIC ACID CRYSTALS

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/8502

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dc.creator Christensen, R. L. en_US
dc.creator Hudson, Bruce S. en_US
dc.creator Kohler, Bryan E. en_US
dc.date.accessioned 2006-06-15T13:20:41Z
dc.date.available 2006-06-15T13:20:41Z
dc.date.issued 1970 en_US
dc.identifier 1970-P-7 en_US
dc.identifier.uri http://hdl.handle.net/1811/8502
dc.description Author Institution: Department of Chemistry, Harvard University en_US
dc.description.abstract Polarized low-temperature absorption, excitation and emission spectra of single crystals of all-trans retenoic acid will be discussed. Both the monoclinic form and a form optically identical to the triclinic modification have been investigated. These results can be interpreted with reference to the known crystal structure to establishthat the main absorption and emission are polarized along the conjugated chain. The crystal results are consistent with photoselection experiments and indicate that the absorption and emission are of $\pi\pi^{*}$ character. Further quantitative interpretation of the single crystal results in terms of the electronic structure of the free molecule will be presented. en_US
dc.format.extent 72340 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title SOLID STATE ELECTRONIC SPECTRA OF RETENOIC ACID CRYSTALS en_US
dc.type article en_US