# THE FAR INFRARED SPECTRUM OF $H_{2}O_{2}^{*}$

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 Title: THE FAR INFRARED SPECTRUM OF $H_{2}O_{2}^{*}$ Creators: Hunt, R. H.; Peters, C. W. Issue Date: 1961 Publisher: Ohio State University Abstract: The absorption of $H_{2}O_{2}$ between 15 nd $150 cm^{-1}$ has been examined with a grating spectrometer (0.3 to $0.5 cm^{-1}$ resolution). The interpretation of most of the strong lines (a series of doublets) is consistent with that of Massey and $Bianco^{1}$ for the microwave spectrum: that $H_{2}O_{2}$ is a nearly symmetric top with the K levels split by the hindered rotation potential barrier. The observed doublets aries from the transitions $\Delta K = 1$ and $\Delta J = 0$, and yield values of $9.19 cm^{-1}$ for (A--B). and $11.43 cm^{-1}$ for the average splitting of the K levels. Description: $^{*}$ Supported by the Geophysics Res. Direct. of the Air Force Cambridge Res. Lab., A.F.R.D. $\dag$ N S F Fellow. $^{1}$ Massey and Bianco, J. Chem. Phys. 22, 442(1954). Author Institution: Randall Laboratory, University of Michigan URI: http://hdl.handle.net/1811/8137 Other Identifiers: 1961-P-1