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ABSOLUTE INFRARED INTENSITIES OF THE BOROHYDRIDE ION IN SOLID $SOLUTIONS^{*}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/8121

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dc.creator Shull, D. L. en_US
dc.creator Schatz, P. N. en_US
dc.date.accessioned 2006-06-15T13:09:44Z
dc.date.available 2006-06-15T13:09:44Z
dc.date.issued 1961
dc.identifier 1961-M-5 en_US
dc.identifier.uri http://hdl.handle.net/1811/8121
dc.description Author Institution: Department of Chemistry, University of Virginia en_US
dc.description $^{*}$Supported by a grant form the National Science Foundation. $\dag$ Present address: Hercules Powder Company, Wilmington, Delaware. $^{1}$J. van der Elsken, Dissertation, University of Amsterdam (1959). $^{2}$ J.A.A. Ketelaar and J. Van der Eleken, J. Chem. Phys., 50, 336 (1959). en_US
dc.description.abstract Absolute intensities of the fundamental vibrations of the $BH_{4}$-ion have been measured for dilute solid solutions in KCl, Nac1, KBr and CsC1 pellets, After correcting for the Lorentz field and the reaction field produced by the vibration itself, $(\mu)$ the following approximate values of the bond moment an its derivative $\frac{\partial \mu}{\partial r}$ are preferred \[ \mu=0.8d, \frac{\partial \mu}{\partial r}=1.5d/a \] A Study of the frequencies in the various solvents indicates that short range forces may be the most important factor in determining frequency shifts contrary to the conclusion of Ketelaar and van der $Elsken.^{2}$ The present results will be compared with similar work on other molecules. en_US
dc.format.extent 90110 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title ABSOLUTE INFRARED INTENSITIES OF THE BOROHYDRIDE ION IN SOLID $SOLUTIONS^{*}$ en_US
dc.type article en_US