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FAR INFRARED SPECTRA OF SOLID METHYL $HALIDES^{*}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/8063

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Title: FAR INFRARED SPECTRA OF SOLID METHYL $HALIDES^{*}$
Creators: Lafferty, W. J.; Robinson, Dean W.
Issue Date: 1961
Abstract: The infrared spectra of methyl halides condensed rapidly from the vapor onto a window held at liquid nitrogen temperature have been examined from 30 to $130 cm^{-1}$. Two sharp bands are found for each compound which are interpreted as arising from the A- and B- axis librational modes of molecules on the $C_{n}$ crystal sites. Effects of correlation interaction are absent. The behavior of the spectra upon annealing of the deposits will be discussed and interpreted on the basis of possible structures of the rapidly rapidly condensed samples.
URI: http://hdl.handle.net/1811/8063
Other Identifiers: 1961-D-8
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