THE VIBRATIONAL SPECTRA OF FORMATE, ACETATE, AND OXALATE IONS

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Title: THE VIBRATIONAL SPECTRA OF FORMATE, ACETATE, AND OXALATE IONS
Creators: Ito, K.; Bernstein, H. J.
Issue Date: 1955
Publisher: Ohio State University
Abstract: The infrared sepctra of solid sodium formate, acetate, and oxalate and the saturated aqueous solutions have been obtained from 3 - 33 $\mu$. The Raman sepctra of the solutions have also been obtained with a photoelectric spectrometer, and depolarization ratios have been measured. A complete vibrational assignment is made for a planar formate ion, but only partial assignments have been given for the acetate adn oxalate ions. From the potential constants, the formate ion in solution has a greater OCO angle ($\sim 60$) and shorter bond distance ($\sim0.008$A) than in the crystalline salt.
Description: Author Institution: National Research Council Division of Pure Chemistry
URI: http://hdl.handle.net/1811/7447
Other Identifiers: 1955-P-6
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