OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/52446

Show full item record

Files Size Format View
abstract.gif 55.00Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
nu2_band_Columbus2.ppt 7.206Mb Microsoft PowerPoint View/Open
Slide1.GIF 14.25Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide2.GIF 35.27Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide3.GIF 25.13Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide4.GIF 74.19Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide5.GIF 12.79Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide6.GIF 30.97Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide7.GIF 67.83Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide8.GIF 21.40Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide9.GIF 20.47Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide10.GIF 18.86Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide11.GIF 15.79Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide12.GIF 67.5Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide13.GIF 16.53Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide14.GIF 17.68Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide15.GIF 15.07Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide16.GIF 12.60Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide17.GIF 23.11Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Slide18.GIF 8.073Kb GIF image Thumbnail of FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$

Title: FTIR SPECTRUM AND PERTURBATION ANALYSIS OF THE $\nu_2$ BAND OF $^{15}$NO$_3$
Creators: Shimizu, N.; Fujimori, R.; Tang, J.; Kawaguchi, K.; Ishiwata, T.
Issue Date: 2012
Abstract: In 1987, Friedl and Sander \textbf{91}, 2721 (1987).} reported observation of the FTIR spectrum of the $\nu_2$ band of $^{14}$NO$_3$ in 762 cm$^{-1}$ region, and rotational analysis was carried out for only transitions with K=3. The obtained negative centrifugal distortion constant $D$$_N$ implied presence of perturbation from other states, but the perturbation analysis has not been carried out. In the present study, the $\nu_2$ band of \textrm{$^{15}$NO$_3$} was first observed in 742 cm$^{-1}$ region. In contrast to the case of $^{14}$NO$_3$ , rotational assignments were carried out for K=0, 3, 6, 9, 12, and 15, and transitions with N$\leq$12 were fitted with usual energy level expression for $D$$_{3h}$ molecule. However, when we included higher N transitions up to N=22, an effect of Coriolis interaction from v$_4$=2 appeared in negative $D$$_N$ for K=0 and staggering in K=3. An energy matrix including $\ell$=0 and $\ell$=$\pm$2 of v$_4$=2 and $\ell$=0 of v$_2$ =1 was used to obtain the energy values of v$_2$ =1 , including the Corilis and $\ell$-type resonance terms. From the determined interaction constant between v$_2$ =1 and v$_4$=2 , anharmonic constant k$_{444}$ was estimated, by assuming a mixing of v$_4$=1 and v$_4$=2.
URI: http://hdl.handle.net/1811/52446
Other Identifiers: 2012-TI-05
Bookmark and Share