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OSCILLATOR STRENGTHS AND PREDISSOCIATION RATES FOR RYDBERG COMPLEXES IN $^{12}$C$^{16}$O BETWEEN 92.9 AND 93.4 NM

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/52229

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Title: OSCILLATOR STRENGTHS AND PREDISSOCIATION RATES FOR RYDBERG COMPLEXES IN $^{12}$C$^{16}$O BETWEEN 92.9 AND 93.4 NM
Creators: Eidelsberg, M.; Lemaire, J. L.; Federman, S. R.; Stark, G.; Heays, A. N.; Gavilan, L.; Fillion, J. H.; Rostas, F.; Lyons, J. R.; Smith, P. L.; De Oliveira, N.; Joyeux, D.; Roudjane, M.; Nahon, L.
Issue Date: 2012
Abstract: We are conducting experiments on the DESIRS beam-line at the SOLEIL Synchrotron to acquire the necessary data on oscillator strengths and predissociation rates for modeling CO photochemistry in astronomical environments. A VUV Fourier Transform Spectrometer provides a resolving power of about 350,000, allowing us to discern individual lines in electronic transitions. Here we focus on results for six overlapping bands seen in spectra of $^{12}$C$^{16}$O and compare them with earlier determinations. Absorption from the ground electronic level, $X$ $^1\Sigma^+$ $v^{\prime\prime}~=~0$, to the upper levels 4p$\pi$(2), II $^1\Pi$, 4p$\sigma$(2), 5p$\pi$(0), 5p$\sigma$(0), and I $^1\Pi$ was analyzed. Our results are the first to provide data on each band. The spectra also reveal a continuum feature that was modeled, but its identification is not known at the present time.
URI: http://hdl.handle.net/1811/52229
Other Identifiers: 2012-RC-07
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