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THE OPTICAL STARK SPECTRUM OF THE $[11.9]$$\Omega=3/2-X^{3}\Pi_{3/2}$ BAND SYSTEM OF PLATINUM MONOFLUORIDE, PtF

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/52199

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Title: THE OPTICAL STARK SPECTRUM OF THE $[11.9]$$\Omega=3/2-X^{3}\Pi_{3/2}$ BAND SYSTEM OF PLATINUM MONOFLUORIDE, PtF
Creators: Qin, Chengbing; Steimle, Timothy C.
Issue Date: 2012
Abstract: Recently the O'Brien group {\textbf{265}} 39, 2011.} reported on the field-free detection and analysis of the [11.9]$\Omeiga=3/2-X^{2}\Pi_{3/2}$ band system of PtF using intracavity laser absorption. The hollow cathode condition limited the spectral resolution, which was insufficient to fully resolved the hyperfine splitting of $^1^9^5$Pt (I=1/2) and $^1^9$F (I=1/2). Here we report laser-induced fluorescence spectra of the 1-0 and 0-0 bands of the [11.9]$\Omeiga=3/2-X^{2}\Pi_{3/2}$ transition of PtF, obtained at near natural linewidth resolution (FWHM ~40MHz) using supersonic molecular beam techniques. The spectra show a complex, cleraly resolved hyperfine structure which has siginificant contributions from magnetic term in $^1^9^5$Pt and $^1^9$F. The spectra of $^1^9^4$PtF, $^1^9^5$PtF, $^1^9^6$PtF, $^1^9^8$PtF isotopogues have been assigned and analyzed. The electric field induced dependence of the R(1.5) branch of the $^1^9^5$PtF isotopogue was analyzed to produce permanent electric dipole moment, $\mu$, of 3.45 D and 2.32 D for the $X^{2}\Pi_{3/2}$ and [11.9]$\Omega=3/2$ states, respectively. A comparision with Ab Initio prediction {\textbf{23}} 564, 2001.}$^,$, {\textbf{39}} 2023, 2000} will be given.
URI: http://hdl.handle.net/1811/52199
Other Identifiers: 2012-RA-02
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