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ELECTRONIC TRANSITIONS OF PALLADIUM MONOBORIDE AND PLATINUM MONOBORIDE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/52198

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Title: ELECTRONIC TRANSITIONS OF PALLADIUM MONOBORIDE AND PLATINUM MONOBORIDE
Creators: Ng, Y. W.; Pang, H. F.; Wong, Y. S.; Qian, Yue; Cheung, A. S-C.
Issue Date: 2012
Abstract: Electronic transition spectrum of palladium monoboride (PdB) and platinum (PtB) monoboride have been studied using the technique of laser-ablation/reaction free jet expansion and laser induced fluorescence spectroscopy. The metal monoborides were produced by reacting laser ablated metal atoms and diborane ((B$_2$H$_6$) seeded in argon. Five and six vibrational bands were observed respectively for the PdB and PtB molecules. Preliminary analysis of the rotationally resolved structure showed that both molecules have X$^{2} \Sigma^{+}$ ground state. Least-squares fit of the measured line positions yielded molecular constants for the electronic states involved. Molecular and electronic structures of PdB and PtB are discussed using a molecular orbital energy level diagram.
URI: http://hdl.handle.net/1811/52198
Other Identifiers: 2012-RA-01
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