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DOES WATER PREFER TO DONATE A PROTON TO AN F OR TO a Cl ATOM? - A ROTATIONAL STUDY OF CH$_{3}$CHClF...H$_{2}$O

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/49678

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dc.creator Feng, Gang en_US
dc.creator Evangelisti, Luca en_US
dc.creator Caminati, W. en_US
dc.creator Favero, Laura B. en_US
dc.creator Grabow, Jens-Uwe en_US
dc.creator Xia, Zhining en_US
dc.date.accessioned 2011-07-12T17:39:39Z
dc.date.available 2011-07-12T17:39:39Z
dc.date.issued 2011 en_US
dc.identifier 2011-MH-04 en_US
dc.identifier.uri http://hdl.handle.net/1811/49678
dc.description Author Institution: Dipartimento di Chimica "G. Ciamician" dell'Universita, Via Selmi 2, I-40126 Bologna, Italy; Istituto per lo Studio dei Materiali Nanostrutturati (ISMN, Sezione di Bologna), CNR; Via Gobetti 101, I-40129 Bologna, Italy; Lehrgebiet Physikalische Chemie A, Institut fur Physikalische; Chemie und Elektrochemie, Universtat Hannover, Callinstr. 3A, D-30167 Hannover, Germany; Chemistry and Chemistry Engineering College, Chongqing University, Chongqing, 400030, P. R. China en_US
dc.description.abstract We measured the molecular beam Fourier transform microwave spectra of six isotopologues of the 1:1 adduct of CH$_{3}$CHClF with water. The water prefers to form an O-H...F rather than an O-H...Cl hydrogen bond. This is exactly the contrary of what observed in the chlorofluoromethane-water adduct, where a O-H...Cl link was formed . Besides the rotational constants, the quadrupole coupling constants of the chlorine atom have been determined. In addition, information on the internal dynamics has been obtained. en_US
dc.language.iso en en_US
dc.title DOES WATER PREFER TO DONATE A PROTON TO AN F OR TO a Cl ATOM? - A ROTATIONAL STUDY OF CH$_{3}$CHClF...H$_{2}$O en_US
dc.type Article en_US