DOES WATER PREFER TO DONATE A PROTON TO AN F OR TO a Cl ATOM? - A ROTATIONAL STUDY OF CH$_{3}$CHClF...H$_{2}$O

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/49678

Show full item record

Files Size Format View
abstract.gif 52.78Kb GIF image Thumbnail of DOES WATER PREFER TO DONATE A PROTON TO AN F OR TO a Cl ATOM? - A ROTATIONAL STUDY OF CH$_{3}$CHClF...H$_{2}$O

Title: DOES WATER PREFER TO DONATE A PROTON TO AN F OR TO a Cl ATOM? - A ROTATIONAL STUDY OF CH$_{3}$CHClF...H$_{2}$O
Creators: Feng, Gang; Evangelisti, Luca; Caminati, W.; Favero, Laura B.; Grabow, Jens-Uwe; Xia, Zhining
Issue Date: 2011
Publisher: Ohio State University
Abstract: We measured the molecular beam Fourier transform microwave spectra of six isotopologues of the 1:1 adduct of CH$_{3}$CHClF with water. The water prefers to form an O-H...F rather than an O-H...Cl hydrogen bond. This is exactly the contrary of what observed in the chlorofluoromethane-water adduct, where a O-H...Cl link was formed . Besides the rotational constants, the quadrupole coupling constants of the chlorine atom have been determined. In addition, information on the internal dynamics has been obtained.
Description: Author Institution: Dipartimento di Chimica "G. Ciamician" dell'Universita, Via Selmi 2, I-40126 Bologna, Italy; Istituto per lo Studio dei Materiali Nanostrutturati (ISMN, Sezione di Bologna), CNR; Via Gobetti 101, I-40129 Bologna, Italy; Lehrgebiet Physikalische Chemie A, Institut fur Physikalische; Chemie und Elektrochemie, Universtat Hannover, Callinstr. 3A, D-30167 Hannover, Germany; Chemistry and Chemistry Engineering College, Chongqing University, Chongqing, 400030, P. R. China
URI: http://hdl.handle.net/1811/49678
Other Identifiers: 2011-MH-04
Bookmark and Share