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C...H...N HYDROGEN BOND FORMATION IN TRIMETHYLAMINE DIMER UPON ONE-PHOTON IONIZATION

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/49669

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Title: C...H...N HYDROGEN BOND FORMATION IN TRIMETHYLAMINE DIMER UPON ONE-PHOTON IONIZATION
Creators: Nakayama, Yuichiro; Matsuda, Yoshiyuki; Fujii, Asuka
Issue Date: 2011
Abstract: Structures of trimethylamine dimer cluster cations which are generated by the vacuum-ultraviolet photoionization are investigated by a combination of infrared spectroscopic methods and theoretical reaction-pass calculations. In the trimethylamine dimer cluster cation, a proton of a methyl group is shared with the N atom of the other trimethylamine moiety. This is evidence that the methyl group acts as a proton donor in the cation state.
URI: http://hdl.handle.net/1811/49669
Other Identifiers: 2011-MG-08
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