OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/49650

Show full item record

Files Size Format View
abstract.gif 42.07Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
MG_H2PO.pptx 1.254Mb Microsoft PowerPoint 2007 View/Open
Slide1.GIF 33.15Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide2.GIF 25.82Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide3.GIF 76.65Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide4.GIF 29.29Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide5.GIF 100.2Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide6.GIF 35.89Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide7.GIF 43.74Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide8.GIF 43.16Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide9.GIF 59.44Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide10.GIF 25.47Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide11.GIF 37.87Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide12.GIF 42.15Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide13.GIF 44.69Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide14.GIF 58.79Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide15.GIF 48.85Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide16.GIF 46.38Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide17.GIF 24.44Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Slide18.GIF 24.72Kb GIF image Thumbnail of THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL

Title: THE ELECTRONIC SPECTRUM OF H$_2$PO, THE PROTOTYPICAL PHOSPHORYL FREE RADICAL
Creators: Gharaibeh, Mohammed A.; Clouthier, Dennis J.
Issue Date: 2011
Abstract: The electronic spectrum of the H$_2$PO radical has been identified by laser-induced fluorescence (LIF) and single vibronic level (SVL) emission techniques. The radical was produced in a pulsed electric discharge jet using a precursor mixture of phosphine (PH$_3$) and carbon dioxide in high-pressure argon and the $\tilde{B}$$^2$A$^{\prime}$ - $\tilde{X}$$^2$A$^{\prime}$ electronic transition was detected in the 410-338 nm region. Low resolution LIF and SVL emission spectra of H$_2$PO and D$_2$PO have been recorded and the $a^{\prime}$ vibrational frequencies have been determined in both states. High-resolution spectra of the 0$_0^0$ bands of H$_2$PO and D$_2$PO, which consist of strong $a$-type and weaker $c$-type components, were recorded. The spectra have been rotationally analyzed and the excited state molecular structure determined. The spectrum of H$_2$PO will be discussed in comparison with the spectra of other phosphoryl and arsenyl radicals that have been recently studied in our laboratory.
URI: http://hdl.handle.net/1811/49650
Other Identifiers: 2011-MF-05
Bookmark and Share