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A LOOK AT A SERIES OF ALKYL AND PERFLUOROALKYL BROMIDES AND CHLORIDES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/49361

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Title: A LOOK AT A SERIES OF ALKYL AND PERFLUOROALKYL BROMIDES AND CHLORIDES
Creators: Long, Brittany E.; Cooke, Stephen A.; Grubbs, Garry S., II
Issue Date: 2011
Abstract: The pure rotational spectrum for bromoperfluoroethane between 8.0 and 14.0 GHz and chloroperfluoroethane between 8.0 and 16.0 GHz has been measured on a chirped pulse Fourier transform microwave spectrometer for the first time. A total of 839 transitions for the bromoperfluoroethane, which includes the $^{79}$Br, $^{81}$Br parent isotopologues and the four $^{13}$C's, have been assigned quantum numbers. 496 transitions were observed for chloroperfluoroethane, which includes the $^{35}$Cl and $^{37}$Cl species. Only the $trans$ conformers were observed for which the rotational constants are reported. Nuclear electric quadrapole coupling constants have been determined and reported. Also, two dipole forbidden/quadrapole allowed $\Delta J$ = 2 transitions were observed in only the bromoperfluoroethane spectra. No forbidden transitions were observed in the chloroperfluoroethane.
URI: http://hdl.handle.net/1811/49361
Other Identifiers: 2011-RH-03
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