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QUADRUPLY BONDED M$_2$ COMPLEXES INCORPORATING THIENYLETHYNYL AND THIENYLVINYL CARBOXYLATES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/46387

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Title: QUADRUPLY BONDED M$_2$ COMPLEXES INCORPORATING THIENYLETHYNYL AND THIENYLVINYL CARBOXYLATES
Creators: Reed, Carly R.; Chisholm, Malcolm H.; Turro, Claudia
Issue Date: 2010
Abstract: Quadruply bonded metal complexes, where M = Mo, W, that incorporate thienylethynyl and thienylvinyl carboxylates are being synthesized. Varying the bond order of the C$_{2}$ unit between the thienyl group and the carboxylate tether provides a series of complexes in which a comparative study on the electronic delocalization in the ground and excited states can be conducted. The properties of these complexes will be predicted by DFT calculations and probed by steady-state absorbance, emission, electrochemistry, and ns- and fs-transient absorption.
URI: http://hdl.handle.net/1811/46387
Other Identifiers: 2010-TF-14
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